Poonam C. Kumar, E. Thomas, Daniel R. Tray
Oct 1, 2001
Citations
0
Influential Citations
4
Citations
Journal
Journal of the Brazilian Chemical Society
Abstract
2-Methoxy(2-tributylstannylethylidene)cyclohexane 16 undergoes stereoselective transmetalation on treatment with tin(IV) chloride to generate the allyltin trichloride 19 which reacts with aldehydes to give the (Z)-(3-hydroxyalkylidene)-2-methoxycyclohexanes 17a-g with excellent 1,5-stereocontrol.