Valérie Martin, H. Molines, C. Wakselman
Mar 1, 1995
Citations
0
Influential Citations
4
Citations
Journal
Journal of Fluorine Chemistry
Abstract
Abstract A two-step synthesis of 1-bromo-4,4,4-trifluoro-3-(trifluoromethyl)but-2-ene in 35% overall yield is reported starting from commercially available hexafluoroacetone. The electrophilic reactivity of this new compound towards various nucleophilic reagents has been studied. Substitution products or ones arising from allylic rearrangement are obtained depending on the nature of the nucleophile.