I. Leban, A. L. Marechal, A. Robert
Nov 15, 1997
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Journal
Acta Crystallographica Section C-crystal Structure Communications
Abstract
The hydrolysis of 2-acetylimino-4-(4-chlorophenyl)-1,3-oxathiole-5-carbonitrile in air results in 2-(4-chlorophenyl)-2-(N-acetylcarbamoylthio)ethanoic acid, which forms a 1:1 adduct with a solvent acetonitrile molecule, C 11 H 10 ClNO 4 S.C 2 H 3 N. Even after ring opening there still exists a short intramolecular S...O interaction [2.660 (3) A]. The bond lengths are normal and in agreement with expected values.