A. Reznikov, N. K. Skvortsov
Feb 1, 2008
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Journal
Russian Journal of General Chemistry
Abstract
Abstract[2-(6,6-Dimethylbicyclo[3.1.1]hept-2-enyl)ethyl]diphenylphosphine and the corresponding phosphine oxide, that hold promise as ligands in metal complex catalysis, were synthesized on the basis of (1R)-(-)-nopol. A Pd(II) bisphosphine complex is obtained on the basis of the synthesized phosphine. When the system [PdCl2(COD)]-[2-(6,6-dimethylbicyclo[3.1.1]hept-2-enyl)ethyl]diphenylphosphine oxide is used as catalyst in the reaction of cyclohexa-1,3-diene with trichlorosilane, asymmetric induction occurs.