J. Sopková-de Oliveira Santos, A. Bouillon, J. Lancelot
Aug 15, 2004
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Influential Citations
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Citations
Journal
Acta crystallographica. Section C, Crystal structure communications
Abstract
The crystal structure of the first reported non-substituted N-methyldioxazaborocane confirms that the presence of a methyl group attached to the N atom introduces an N\rightarrowB bond length that is longer than that in a simple dioxazaborocane ring. The presence of more N atoms in the vicinity of the B atom in the title compound [systematic name: 6a-(6-bromopyridin-2-yl)-3a-methyl-2,3,4,5-tetrahydro-1,6-dioxa-3a-aza-6a-borapentalene], C10H14BBrN2O2, does not modify significantly any structural parameter in the dioxazaborocane ring. On the other hand, a small asymmetry appears in the bond angles of the pyridine C atom next to the B atom.