D. E. Grocock, G. Hallas, J. Hepworth
1971
Citations
0
Influential Citations
1
Citations
Journal
Journal of The Chemical Society B: Physical Organic
Abstract
Attempts to synthesise 2-dimethylaminobenzylidyne trifluoride (2-trifluoromethyl-NN-dimethyl aniline) have, so far, been unsuccessful. The possible relevance of steric factors and intramolecular hydrogen bonding operative in 2-amino- and 2-methylaminobenzylidyne trifluoride (2-trifluoromethyl- and 2-trifluoromethyl-N-methyl-anline) is discussed by comparing observed and calculated dipole moments of these compounds and by assessing their tendencies to undergo intermolecular hydrogen bonding to dioxan.