O. Ganina, S. G. Zamotaeva, M. A. Nosarev
Jul 1, 2005
Citations
0
Influential Citations
4
Citations
Journal
Russian Chemical Bulletin
Abstract
Abstract2-(Azidomethyl)phenyllead triacetate was obtained by the reaction of 2-(azidomethyl)phenylboronic acid with lead tetraacetate. A strategy for the synthesis of isoquinoline derivatives was proposed that involves a reaction of this organolead reagent with enolizable substrates followed by annelation in the presence of triphenylphosphine. The use of 2-(azidomethyl)phenylboronic acid allowed α-arylation products to be obtained from β-diketones and natural β-oxo lactones in good yields.