J. Flores, A. L. C. Chien, M. Rausch
Dec 2, 1996
Citations
0
Influential Citations
29
Citations
Journal
Macromolecules
Abstract
[2-(Dimethylamino)ethyl]-substituted cyclopentadienyltitanium complexes (3−6) have been synthesized and characterized. Structural data indicates intramolecular coordination of the dimethylamino group to titanium. The catalytic activities and selectivities for styrene, ethylene, and propylene polymerization with 3−6 have been compared with the reference compounds CpTiCl3 (1), Cp*TiCl3 (2), and Cp2TiCl2 (7), and are consistent with Ti−N Lewis acid−base interaction.