N. Maezaki, A. Furusawa, Y. Hirose
Apr 29, 2002
Citations
0
Influential Citations
9
Citations
Journal
Tetrahedron
Abstract
Abstract We have developed new phosphorylating agents, 3-phosphono-2-( N -cyanoimino)-thiazolidine derivatives (3-phosphono-NCTs), which were readily synthesized by phosphorylation of NCT, and transformed primary and secondary alcohols into phosphates in good yield. The transfer of three kinds of dialkylphosphono groups [(PhO) 2 P(O)–, (EtO) 2 P(O)–, (Cl 3 CCH 2 O) 2 P(O)–] proceeded in excellent yields. Selective phosphorylation of various alcohols was also accomplished.