G. Gainsford, A. Luxenburger
Jan 14, 2012
Citations
0
Influential Citations
0
Citations
Journal
Acta Crystallographica Section E: Structure Reports Online
Abstract
The title compound, C29H35NO6.0.334C3H8O, a novel chiral N-(fluoren-9-ylmethyloxyxcarbonyl) precursor, crystallizes with two independent carbamate (M) molecules and propan-2-ol solvent molecules in the unit cell. Its crystal structure has been determined from barely adequate data obtained from a multi-fragment needle crystal. In the crystal, N—H⋯O hydrogen bonds link M molecules related by translation along the a axis into two independent chains. The ordered solvent molecule, having a partial occupancy of 0.334, is attached to one independent M molecule through O—H⋯O hydrogen bonds. The crystal packing exhibits weak intermolecular C—H⋯O interactions and voids of 270 Å3 filled with randomly disordered solvent molecules which were handled using the SQUEEZE methodology.