Nadège Faux, E. Labbé, O. Buriez
Feb 15, 2007
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Journal
Journal of Electroanalytical Chemistry
Abstract
Abstract We report in this paper an electroanalytical study of the reaction of 1-halonaphthalenes with electrogenerated [Co I -salen]. With 1-iodonaphthalene, the reaction observed is a substitution, with a release of the iodide ion. Conversely, the reaction is much slower with 1-bromonaphthalene, and the intermediate adduct is observed at the time scale of cyclic voltammetry. The corresponding rate constants have been determined.