V. F. Kuznetsov, A. Lough, D. Gusev
Oct 11, 2002
Citations
0
Influential Citations
13
Citations
Journal
Chemical communications
Abstract
This communication reports the preparation of a novel trans-chelating diphosphine, 1,5-bis(di-tert-butylphosphino)-2-(S)-dimethylaminopentane, that undergoes triple C-H activation in reaction with [RuCl2(p-cymene)]2 to give a chiral square-pyramidal 16-electron carbene complex of ruthenium.