T. A. Pudova, F. K. Velichko, L. I. Terekhova
Jun 1, 1973
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Journal
Russian Chemical Bulletin
Abstract
1. We were the first to effect the homolytic addition of diethyl dibromomalonate to an unsaturated compound, and high yields of the diethyl dibromomalonate-methyl acrylate adduct were obtained when the reaction was initiated with the system: iron pentacarbonyl + dimethylformamide. 2. It was shown that peroxide initiators have a Low efficiency in this reaction.