R. F. Lang, Telvin D. Ju, G. Kiss
Aug 1, 1994
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0
Influential Citations
19
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Journal
Inorganic Chemistry
Abstract
The complex W(CO){sub 3}(phen)(EtCN) undergoes oxidative addition with disulfides forming the formally 16-electron complexes W(CO){sub 2}(phen)(SR){sub 2}(R=Ph, {sup t}Bu, Me, benzyl). The reactions proceed through intermediates identified spectroscopically as the coordinated disulfide complexes. The rate of oxidative addition of coordinated disulfides is in the order {sup t}BuSSBu{sup t}<