Christopher M. Jessop, A. Parsons, A. Routledge
Oct 3, 2003
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Influential Citations
26
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Journal
Tetrahedron-asymmetry
Abstract
Abstract Intermolecular radical addition of a (1R,2R,3S,5R)-(−)-pinanediol-derived thiophosphite leads to the diastereoselective formation of organophosphorus adducts. Addition of the intermediate phosphonothioyl radical to electron-rich alkenes or alkynes occurs with retention of configuration at phosphorus.