N. M. Karimova, A. Glazkov, A. V. Ignatenko
Jul 1, 2003
Citations
0
Influential Citations
5
Citations
Journal
Russian Chemical Bulletin
Abstract
Ethyl 4,4,4-trifluorocrotonate 1 readily adds aliphatic and aromatic thiols and aminothiols at the double bond in the presence of catalytic amounts of alkylamines and ammonia to give 3-thiolation products. Thiolacetic acid reacts with ester 1 in the absence of a catalyst at 100 °C.