W. E. Bull, S. Madan, J. E. Willis
Apr 1, 1963
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Inorganic Chemistry
Abstract
The preparation of 26 metallic complexes of 14 different metals with N,N- dimethylacetamide (DMA) is reported. The complexes were characterized by their melting points, infrared spectra in the 2 to 15 mu region, electrical conductance in DMA, and magnetic moments. The infrared spectra suggest that coordination through the oxygen of DMA occurs for all the metals investigated. In most instances, the complexes contain fewer moles of DMA than the maximum coordination number of the metal, indicating coordination by halide ion and/or water. (auth)