N. Meyer, Karolin Löhnwitz, A. Zulys
Jun 20, 2006
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Journal
Organometallics
Abstract
The dimeric complexes 2-(isopropylamino)troponate zinc methyl and ethyl [(iPrAT)Zn-R]2 (R = Me (2a), Et (2b)) were synthesized by reaction of (iPrAT)H with dimethyl and diethyl zinc, respectively, in toluene at low temperature. Reacting (iPrAT)H with dimethyl zinc at elevated temperature resulted in the double-substituted complex [(iPrAT)2Zn] (3). Compounds 2a,b, which were investigated by single-crystal X-ray diffraction, are dimeric in the solid state. The metal centers are bridged asymmetrically by two (μ)-oxygen atoms; thus a flat Zn−O−Zn‘−O‘ plane is observed. Compounds 2a,b were used as the catalyst in the intramolecular hydroamination reaction of nonactivated terminal aminoolefins and one aminoalkyne. Good catalytic activities at elevated temperature were observed.