M. Branca, A. Gamba, C. Oliva
Mar 1, 1983
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0
Influential Citations
4
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Journal
Chemical Physics
Abstract
Abstract The internal rotation in the free anion radicals and the ion pairs from 3-nitroacetophenone and 4-nitroacetophenone is studied on the basis of their dynamic EPR spectra in solution. Energy barriers and related thermodynamic parameters which govern internal rotation and rotational diffusion of the studied systems have been provided together with a discussion about the accuracy and the reliability of their determination.