R. Bromilow, K. A. Lord
Oct 27, 1976
Citations
0
Influential Citations
8
Citations
Journal
Journal of Chromatography A
Abstract
Abstract Carbamates injected into the gas—liquid chromatograph with trimethylphenylammonium hydroxide react to give dervatives with good gas—liquid chromatographic properties. Oximecarbamates yield methoximes by this procedue, and substituted-phenyl N-methylcarbamates yield anisoles. Yields over a range of conditions were generally better than 90%, except from aldoximecarbamates where competing reactions intervened. Although only sulphor-containing carbamates were studied, it should be possible to extend the reaction to other carbamates.