K. Langille, M. Peach
Apr 1, 1972
Citations
0
Influential Citations
36
Citations
Journal
Journal of Fluorine Chemistry
Abstract
Abstract The nucleophilic substitution of hexafluorobenzene, decafluorobiphenyl, and hexachlorobenzene with the thiolate anion, RS- (R = H, Me, Et, Ph, C 6 F 5 ) has been studied. Compounds of the type C 6 F 5 SR, C 6 (SR) 2 F 4 , C 6 F 2 (SR) 4 , RSC 6 F 4 ·C 6 F 4 SR, (RS) 3 F 2 C 6 ·C 6 F 2 (SR) 3 , C 6 (SR) 2 Cl 4 and C 6 Cl 2 (SR) 4 were isolated as major products. The new compounds were characterized by elemental analysis, infrared, Raman, mass and NMR spectra.