J. S. Fleming, K. Mann, C. Carraz
May 18, 1998
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Journal
Angewandte Chemie
Abstract
The templating effect of the tetrafluoroborate ion leads to assembly of four CoII ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but with NiII a simpler dinuclear complex forms.