D. Crich, Maheswaran S. Karatholuvhu
Jun 5, 2008
Citations
0
Influential Citations
15
Citations
Journal
The Journal of organic chemistry
Abstract
4-Trifluoromethylbenzenepropargyl ethers are stable and sterically minimal alcohol protecting groups that are readily cleaved in a single step by exposure to lithium naphthalenide. In conjunction with the 4,6-O-benzylidene protecting group, glycosylation reactions of 2-O-(4-trifluoromethylbenzenepropargyl)-protected mannosyl donors are extremely beta-selective.