Song Li-min
2007
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Journal
Hebei Chemical Engineering and Industry
Abstract
The recent progress and the application of sodium azide in organic synthesis,including the synthesis of tetrazole compounds, the preparation of triazole compounds, the synthesis of isocyanates by Curtius rearrangement reaction, the synthesis of azide compounds, the direct conversion of carboxylic acids into carbamates, the formation of β-azidocarbonyl compounds by reaction with cyclic enones, the synthesis of 1-aryl-1 H-benzotriazoles, the synthesis of amides,the synthesis of α-azidoketones, the synthesis of 3-cyanoindoles, the ring opening reactions of epoxides and aziridines, and reduction of 1,4-benzoquinones to hydroquinones were reviewed.