A. Smagin, V. Matyukha, V. P. Korobtsev
Oct 1, 1997
Citations
1
Influential Citations
11
Citations
Journal
Journal of Power Sources
Abstract
Abstract Lithium hexafluorophosphate, isolated from hydrogen fluoride solution (anhydrous) by decanting and filtering, is an adduct of composition LiPF 6 * HF. By thermogravimetric investigations the dynamics of HF removal from LiPF 6 by LiPF 6 * HF thermal decomposition was studied. Based on the experimental data the constants entering into the equations as C = C 0 * exp( t * K 0 * exp(− E/RT )) were calculated, explaining the thermal decomposition processes of LiPF 6 * HF and LiPF 6 .