S. V. Basenko, A. A. Maylyan, A. Soldatenko
Mar 1, 2018
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0
Influential Citations
3
Citations
Journal
Silicon
Abstract
AbstractA series of derivatives of symmetrical 1,3-dichloro-1,1,3,3-tetraorganyl- and 1,1,3,3-tetrachloro-1,3-diorganyldisiloxanes ClRR’Si-O-SiRR’ (R = Cl, H, CH 3; R’ = CH 3, Et, ClCH 2, Vin, Ph) have been synthesized by a novel efficient reaction of corresponding diorganyldichlorosilane and organyltrichlorosilane RSiCl 3 (3–5-fold excess) with dimethyl sulfoxide in 53 to 91 % yield. Graphical AbstractNew Approach to the Synthesis of Symmetrical 1,3-Dichloro-1,1,3,3-Tetraorganyl- and 1,1,3,3-Tetrachloro-1,3-Diorganyldisiloxanes