Takeshi Komiyama, Yasunori Minami, T. Hiyama
Dec 19, 2016
Citations
0
Influential Citations
24
Citations
Journal
Angewandte Chemie
Abstract
Aryl(triethyl)silanes are found to undergo cross-coupling with iodoarenes in the presence of catalytic amounts of CuBr2 and Ph-Davephos, as well as cesium fluoride as a stoichiometric base. Because the silicon reagents are readily accessible through catalytic C-H silylation of aromatic substrates, the net transformation allows coupling of aromatic hydrocarbons with iodoarenes via triethylsilylation.