F. Cataldo, O. Ursini, G. Angelini
2010
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Influential Citations
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Journal
Radiation Physics and Chemistry
Abstract
Abstract The radiation-induced polymerization of 3-methyl-1,3-pentadiene (3MPD) as an inclusion complex in deoxycholic acid (DOCA) has produced in good yield the optically active polymer poly(3-methyl-1,4-pentadiene) (P3MPD) whose structure and properties were studied by FT-IR spectroscopy and thermal analysis (TGA, DTG and DTA). The data show that the polymer is essentially trans -1,4-P3MPD as expected for the polymerization in constrained media. Trans -1,4-P3MPD is optically active with [ α ] D values comprised between +4.3 and +5.6. The optical rotatory dispersion curve of the P3MPD is completely different from that of DOCA as expected.