Y. Takemoto, Y. Baba, I. Noguchi
May 1, 1996
Citations
0
Influential Citations
6
Citations
Journal
Tetrahedron Letters
Abstract
The reaction of meso-2,4-hexadien-1,6-dial Fe(CO)3 complex 1 with several alkylzincs in the presence of 50 mol% of (S)-(+)-diphenyl-(1-methylpyrrolidin-2-yl) methanol 4a proceeded with high enantiotopic group- and face-selectivity to give (2R,6S)-mono alcohol complexes 2a-c as major products (>90% de and >98% ee).