S. Sato, H. Kato, M. Ohta
Dec 1, 1967
Citations
0
Influential Citations
20
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
The reaction of 2-phenylazirine (I) with acid chlorides, anhydrides, an imidoyl chloride, and carboxylic acids were investigated. When I was treated with acid chlorides and anhydrides, the corresponding 2, 5-disubstituted oxazole derivatives were obtained. The reaction of I with phthalic and maleic anhydride, however, gave ring-cleavage products. The reaction of I and N-phenylbenzimidoyl chloride gave 1,2, 5-triphenylimidazole. On the other hand, I and benzoic and thiobenzoic acid gave N-benzoylphenacylamine and N-benzoyl-α-benzoylthio-β-aminostyrene respectively.