F. Gu, Huilong Dong, Youyong Li
Sep 30, 2014
Citations
1
Influential Citations
114
Citations
Quality indicators
Journal
Macromolecules
Abstract
The synthesis and characterization of pyrrolidinium cation based anion exchange membranes (AEMs) are reported. Pyrrolidinium cations with various N-substituents (including methyl, ethyl, butyl, octyl, isopropyl, 2-hydroxylethyl, benzyl, and cyclohexylmethyl groups) were synthesized and investigated with respect to their chemical stability in alkaline media. The influence of substitutions on alkaline stability of pyrrolidinium cations was investigated by quantitative 1H nuclear magnetic resonance spectroscopy (NMR) and theoretical approaches. N,N-Ethylmethyl-substituted pyrrolidinium cation ([EMPy]+) exhibited the highest alkaline stability in this study. The synthesized AEMs based on [EMPy]+ show promising alkaline stability in strongly basic solution. The study of this work should provide a feasible way for improving the alkaline stability of pyrrolidinium cation based AEMs.