G. Munno, T. Poerio, G. Viau
1996
Citations
0
Influential Citations
33
Citations
Journal
Chemical Communications
Abstract
A one-pot reaction of Co(NO3)2·6H2O or FeCl2, 2,2′-bipyrimidine (bipym) and NaN3 affords the two [M2-(bipym)(N3)4](M = CoII 1, FeII 2) honeycomb sheetlike compounds with alternating double end-on azide and bis(chelating) bipym bridging groups; magnetic susceptibility measurements indicate that they exhibit ferromagnetic (through the end-on azide) and antiferromagnetic (through bipym) magnetic interactions, their magnetization studies revealing the occurrence of metamagnetic like behaviour.