B. Manhas, S. Kalia
Jun 1, 1996
Citations
0
Influential Citations
2
Citations
Journal
Polyhedron
Abstract
Abstract Five compounds of the general formula Fe(NO)(L)n (n = 2, L = 4-methylpiperazine-l-carbodithioate, 4-phenylpiperazine-l-carbodithioate, thiomorpholine-N-carbodithioate, piperidine-N-carbodithioate; n = 1, L = 2-methylpiperazine-1,4-dicarbodithioate) have been prepared and characterized by elemental analyses, IR spectral studies and room- and liquid-nitrogen-temperature magnetic susceptibility measurements. Two of these complexes have also been subjected to variable-temperature magnetic susceptibility measurements. The temperature dependence of μeff has been correlated with a S = 3 2 ← S = 1 2 spin-crossover phenomenon.