F. Neve, M. Ghedini, G. Munno
Apr 1, 1991
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Influential Citations
14
Citations
Journal
Organometallics
Abstract
The reaction of 2-phenylpyridine (ppyH) or 8-methylquinoline (mqH) with [trans-Ir(CO)(CH 3 CN)-(PPh 3 ) 2 ]PF 6 at 25 o C gives the four-coordinate complex [Ir(CO)(HL)(PPh 3 ) 2 ]PF 6 (2, HL=ppyH; 3, HL=mqH), wherein the ligands is N-coordinated. All complexes have been characterized by 1 H, 31 P, and 13 C NMR spectroscopies. The molecular structure of 3 has been determined by X-ray analysis. The complex is monoclinic, space group C2/c