Xiao Fu, Zhiyong Jiang, Choon‐Hong Tan
Nov 29, 2007
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Chemical Communications
Abstract
Chiral bicyclic guanidine has been found to catalyze the phospha-Michael reactions of diaryl phosphine oxide to nitroalkenes with high enantioselectivities, offering a direct methodology to prepare chiral β-aminophosphine oxides and β-aminophosphines.