J. Baiano, D. L. Carlson, G. Wolosh
Jun 1, 1990
Citations
0
Influential Citations
49
Citations
Journal
Inorganic Chemistry
Abstract
Mono- and bimetallic complexes of Re(CO) 3 Cl containing the bidentate, bridging ligands 2,3-bis(2-pyridyl) pyrazine (dpp), 2,3-bis(2-pyridyl) quinoxaline (dpq), and 2,3-bis(2-pyridyl) benzo [g] quinoxaline (dpb) have been prepared and characterized. The synthesis and characterization of the new bidentate bridging ligand dpb are reported. The lowest energy electronic absorption band has been assigned as a metal-to-ligand charge-transfer (MLCT) process, where the acceptor state is localized primarily on the bridging ligand