E. Meštrović, I. Halasz, Dejan-Krešimir Bučar
Apr 1, 2004
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0
Influential Citations
6
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Journal
Acta Crystallographica Section E-structure Reports Online
Abstract
In the reaction of bis(1-phenylbutane-1,3-dionato)nickel(II) with dimethyl sulfoxide, the adduct bis(dimethyl sulfoxide)bis(1-phenylbutane-1,3-dionato)nickel(II), [Ni(C10H9O2)2(C2H6OS)2], is formed, in which two dimethyl sulfoxide (DMSO) molecules are coordinated to the Ni atom through their O atoms in a trans arrangement. The compound crystallizes in space group P21/a with the Ni atom lying on a center of inversion. The coordination polyhedron around the Ni atom is a distorted octahedron. The chelate ring deviates slightly from planarity. The Ni—O bond distance to the DMSO O atom is slightly longer than that to the 1-phenyl;butane-1,3-dionate ligand. In the crystal structure, two-dimensional frameworks are formed by C–H⋯O interactions.