M. Alagar, K. Rajagopal, R.V. Krishnakumar
Jul 1, 2003
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0
Influential Citations
6
Citations
Journal
Acta Crystallographica Section E-structure Reports Online
Abstract
In the title compound, [UO2(C15H11O2)2(C18H15OP)] or [UO2(DBM)2(Ph3PO)], where DBM is dibenzoyl methanate, the UVI atom is coordinated by seven O atoms in a distorted pentagonal–bipyramidal geometry. The diphenylpropane-1,3-dionate system acts as a chelating ligand and coordinates through both of its ketonate O atoms and the triphenyl phosphine oxide ligand coordinates through the O atom. The U—O distances range from 1.759 (4) to 2.385 (4) A.