J. F. Allan, K. Henderson, A. Kennedy
1999
Citations
0
Influential Citations
23
Citations
Journal
Chemical Communications
Abstract
Bis(hexamethyldisilazido)magnesium has successfully been used to mediate aldol additions of selected ketones and aldehydes in hydrocarbon media, and the structure of an intermediate amido(aldolate), [{(Me3Si)2NMg[µ-OC(Me)- ButCH2C(But)=O]}2] 17, produced by the self-coupled reaction of pinacolone has been characterised by X-ray crystallography.