R. Corriu, N. Escudié, C. Guérin
Mar 20, 1984
Citations
0
Influential Citations
22
Citations
Journal
Journal of Organometallic Chemistry
Abstract
Abstract Reactions of 1,3-bis(trimethylsilyl)propene with carbonyl compounds in the presence of fluoride ions as catalysts, produce selectively ( E )-1-trimethylsilylbut-1-en-4-ol. 1,3-Bis(trimethylsilyl)propenyllithium reacts with carbonyl compounds, under formation of 1-trimethylsilylated dienes. The reactions of these dienes with Fe(CO) 5 , Fe 2 (CO) 9 and (MeCp)Mn(CO) 3 are reported; they are good precursors for η 4 -dienyl complexes.