A. Nesmeianov, R. Freĭdlina, V. N. Kost
Oct 1, 1958
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Journal
Selected Works in Organic Chemistry
Abstract
1. The reaction of bromination of 1,1,1-trichloropropene under various conditions was examined. 2. The reaction proceeds in a single path in strongly polar media and yields the normal addition product- 1,1,1-trichloro-2,3-dibromopropane. 3. 1,1,2-Trichloro-1,3-dibromopropane, whose formation is explained by a homolytic isomerization of the intermediately formed free radical CCl3ĊHCH2Br →ĊCl2CHClCH2Br, is formed along with 1,1,1-trichloro-2,3-dibromopropane if the reaction is run in nonpolar media under illumination or in the presence of benzoyl peroxide.