Takashi Kippo, Kanako Hamaoka, I. Ryu
Jan 16, 2013
Citations
0
Influential Citations
54
Citations
Journal
Journal of the American Chemical Society
Abstract
Bromine radical-mediated cyclopropylcarbinyl-homoallyl rearrangement of alkylidenecyclopropanes was effectively accomplished by C-C bond formation with allylic bromides, which led to the syntheses of 2-bromo-1,6-dienes. A three-component coupling reaction comprising alkylidenecyclopropanes, allylic bromides, and carbon monoxide also proceeded well to give 2-bromo-1,7-dien-5-ones in good yield.