H. Takahata, H. Ouchi, Motohiro Ichinose
Sep 5, 2002
Citations
0
Influential Citations
44
Citations
Journal
Organic letters
Abstract
C(2)-symmetric 2,6-diallylpiperidine 1-carboxylic acid methyl ester (5) was examined via the double asymmetric allylboration of glutaraldehyde followed by aminocyclization and carbamation as a promising chiral building block for piperidine-related alkaloids, which were synthesized by the desymmetrization of 5 using intramolecular iodocarbamation as a key step. [reaction: see text]