J. Gargulak, W. Gladfelter
1994
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0
Influential Citations
17
Citations
Journal
Inorganic Chemistry
Abstract
Isopropyl- and benzylamine react with (OC-6-32)-dicarbonylbis(methoxycarbonyl) [1,2-bis(diphenylphosphino)ethane]ruthenium(II), at room temperature by substituting rapidly both of the methoxy groups. The bis(carbamoyl) complex (OC-6-32)-dicarbonylbis(N-isopropylcarbamoyl) [1,2-bis(diphenylphosphino)ethane]ruthenium(II) was fully characterized using solution spectroscopy and single-crystal X-ray diffraction [monoclinic crystal system, P2 1 /c spacegroup, a=9.083(3) A, b=22.28(1) A, c=19.599(9) A, β=98.62(3) o , V=3921(10) A 3 , Z=4]