I. Hirao, T. Kito
Nov 1, 1973
Citations
0
Influential Citations
21
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
The yield of the complex was examined using eleven potassium phenoxide or substituted phenoxides. The phenoxide with an electron-donating group gave a complex in a better yield than did that with an electron-attracting group. The infrared spectra of the four complexes were measured. From these results, it was concluded that, in the complex, the carbon atom of carbon dioxide binds to the oxygen atom or the π-electron of alkali phenoxide. The thermal analyses of the complex were also conducted by DTA and TGA in an atmosphere of carbon dioxide; a strong endothermic peak and a rapid weight loss were observed at the temperatures from 120 to 140 °C.