S. Anderson, Stanford D. Mitchell, Kayla A. LaPlante
May 1, 2017
Citations
0
Influential Citations
3
Citations
Journal
Journal of Heterocyclic Chemistry
Abstract
The transamination of 6-chloro-2-(3-chlorophenyl)-1H-benz[de]isoquinoline-1,3-(2H)-dione with primary alkylamines under pseudo-first-order conditions is shown to be unimolecular in both reagents as well as unimolecular in methanol (in methanol solution). The reaction is subject to both general acid and general base catalysis. A termolecular, solvated transition state model and a putative model for the early steps of laser tissue welding with aminonaphthalimide dyes are proposed.