P. Allevi, M. Anastasia, P. Ciuffreda
1987
Citations
0
Influential Citations
13
Citations
Journal
Journal of The Chemical Society, Chemical Communications
Abstract
Readily available 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl chloride smoothly reacts with various silyl enol ethers and silver(I) trifluoromethanesulphonate (triflate) to afford D-C-glucopyranosyl derivatives of α-configuration in high yields, whereas reaction with an electron-rich aromatic nucleophile yields the corresponding β-anomer.