E. Keßenich, T. Klapötke, J. Knizek
Dec 1, 1998
Citations
1
Influential Citations
39
Citations
Journal
European Journal of Inorganic Chemistry
Abstract
2,4-Bis(triphenylphosphanimino)tetrazolo[5,1-a][1,3,5]triazine (1) was synthesized by reaction of cyanuric azide with triphenylphosphane. 1 is characterized by X-ray structural analysis, IR, Raman, and NMR spectroscopy. The obtained spectra showed that the remaining azide group in 1 reacts with the N4 atom of the triazine ring and forms a tetrazole. An improved crystal structure for 2,4,6-triazido-1,3,5-triazine (2) was determined and for the first time a 14N-NMR spectrum was obtained. CAUTION: 2 (Cyanuric azide) is explosive! The explosive nature increases with greater purity and crystal size.