T. Moriuchi, M. Nishiyama, Tomohiko Beppu
May 14, 2007
Citations
0
Influential Citations
8
Citations
Journal
Bulletin of the Chemical Society of Japan
Abstract
4,8-Dihydroxyquinoline-2-carboxylic acid (1) possessing quinoline-N, hydroxy-0, and carboxy-0 donor functions was demonstrated to serve as a tridentate ligand in the complexation with NH 4 VO 3, affording the cis-dioxovanadium(V) complex 2. Each molecule of 2 was found to be packed in a hexagonal molecular arrangement through π-π interaction in the crystal packing, creating a channel cavity which was occupied by water molecules that form a one-dimensional water chain.