F. Abbott, J. Slatter, G. Kang
1986
Citations
0
Influential Citations
2
Citations
Journal
Tetrahedron
Abstract
Abstract The oxidation of (±)-2-ethyl-1,5-dimethyl-3,3-diphenylpyrrolinium perchlorate ( 1 , EDDP) with m-chloroperbenzoic acid (MCPBA) afforded diastereomeric 2-(4',4'-diphenylheptan-5'-one-2'-yl)-oxaziridine ( 2 ), 4,4-diphenyl-2,5-heptanedione ( 3 ), and the known coapounds 2-ethyl-5-methyl-3,3-diphenyl-1-pyrroline ( 5 , EMDPT) and 1,5-dimethyl-3,3-diphenylpyrrolidone ( 4 , DDP). 13C and 1H NMR results for the new compounds and mechanisms for their formation are discussed.